Semiconductor device and manufacturing method thereof

ABSTRACT

In a method of manufacturing a semiconductor device, a thermal treatment is performed on a substrate, thereby forming a defect free layer in an upper layer of the substrate, where a remaining layer of the substrate is a bulk layer. A density of defects in the bulk layer is equal to or more than 1×10 8  cm −3 , where the defects are bulk micro defects. An electronic device is formed over the defect free layer. An opening is formed in the defect free layer such that the opening does not reach the bulk layer. The opening is filled with a conductive material, thereby forming a via. The bulk layer is removed so that a bottom part of the via is exposed. A density of defects in the defect free layer is less than 100 cm −3 .

RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No.15/281,315, filed on Sep. 30, 2016, the entire contents of each of whichapplications are incorporated herein by reference.

TECHNICAL FIELD

The present disclosure relates generally to semiconductor devices and,more particularly, to semiconductor devices having through-silicon vias.

BACKGROUND

Through-silicon vias (TSVs) are formed in a semiconductor wafer byinitially forming an opening at least partially in the semiconductorwafer (e.g., Si substrate), and forming a conductive material in theopening. The TSV electrically connects electronic devices (e.g.,transistors) formed on the front surface of the substrate and a terminalformed at the rear (back) surface of the substrate.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is best understood from the following detaileddescription when read with the accompanying figures. It is emphasizedthat, in accordance with the standard practice in the industry, variousfeatures are not drawn to scale and are used for illustration purposesonly. In fact, the dimensions of the various features may be arbitrarilyincreased or reduced for clarity of discussion.

FIG. 1 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 2 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 3 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 4 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 5 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 6 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 7 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 8 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 9 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a through-silicon via (TSV)structure according to one embodiment of the present disclosure.

FIG. 10 shows an exemplary device structure according to anotherembodiment of the present disclosure.

FIG. 11 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a TSV structure according to oneembodiment of the present disclosure.

FIG. 12 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a TSV structure according to oneembodiment of the present disclosure.

FIG. 13 shows an exemplary cross sectional view illustrating amanufacturing process of a TSV structure according to another embodimentof the present disclosure.

FIG. 14 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a TSV structure according toanother embodiment of the present disclosure.

FIG. 15 shows an exemplary cross sectional view illustrating one of thestages of a manufacturing process for a TSV structure according toanother embodiment of the present disclosure.

DETAILED DESCRIPTION

It is to be understood that the following disclosure provides manydifferent embodiments, or examples, for implementing different featuresof the invention. Specific embodiments or examples of components andarrangements are described below to simplify the present disclosure.These are, of course, merely examples and are not intended to belimiting. For example, dimensions of elements are not limited to thedisclosed range or values, but may depend upon process conditions and/ordesired properties of the device. Moreover, the formation of a firstfeature over or on a second feature in the description that follows mayinclude embodiments in which the first and second features are formed indirect contact, and may also include embodiments in which additionalfeatures may be formed interposing the first and second features, suchthat the first and second features may not be in direct contact. Variousfeatures may be arbitrarily drawn in different scales for simplicity andclarity.

Further, spatially relative terms, such as “beneath,” “below,” “lower,”“above,” “upper” and the like, may be used herein for ease ofdescription to describe one element or feature's relationship to anotherelement(s) or feature(s) as illustrated in the figures. The spatiallyrelative terms are intended to encompass different orientations of thedevice in use or operation in addition to the orientation depicted inthe figures. The device may be otherwise oriented (rotated 90 degrees orat other orientations) and the spatially relative descriptors usedherein may likewise be interpreted accordingly. In addition, the term“made of” may mean either “comprising” or “consisting of.”

FIGS. 1-9 show exemplary cross sectional views illustrating amanufacturing process of a through-silicon via (TSV) structure accordingto one embodiment of the present disclosure. General fabricationoperations of a TSV may be found in U.S. Pat. No. 8,680,682, the entirecontents of which in incorporated herein by reference.

In FIG. 1, a substrate 10 is provided. The substrate 10 has a first(e.g., front) side 11 and a second (rear) side 12 opposite the firstside 11, and may be a bulk silicon wafer, which is doped with impurityor undoped, or an active layer of a silicon-on-insulator (SOI)substrate. The substrate 10 may comprise other semiconductors, such asGroup IV-IV compound semiconductors such as SiC and SiGe, Group III-Vcompound semiconductors such as GaAs, GaP, GaN, InP, InAs, InSb, GaAsP,AlGaN, AlInAs, AlGaAs, GaInAs, GaInP, and/or GaInAsP; or combinationsthereof.

In one embodiment, a Si substrate (wafer) is used. Generally, a siliconwafer as provided by a wafer manufacture includes defects, such as bulkmicro defects (BMDs). BMD generally refer to oxygen precipitates insilicon, and may include oxygen precipitates, voids, inclusions, sliplines, etc. Crystal Originated Particles (or Pits) (COP) may be includedin BMD.

The BMDs in the silicon layer below electronic device (e.g., MOStransistors) act as a gettering site to keep impurities away from theMOS transistors. BMDs can be detected by illuminating a sample with IR(infrared) light and looking at it with a camera that is sensitive toIR.

In one embodiment of the present disclosure, the density of BMDs in thesilicon substrate 10 (initial number) is equal to or more than 1×10⁸cm⁻³. A typical density of BMDs in a silicon wafer formed by a CZ methodmay be defined by industrial standards, such as SEMI Standard or JEITAstandard. The number of BMDs can be determined by counting etch pitscreated by wet etching using KOH.

In the present disclosure, a defect free layer (BMD free layer ordenuded zone) 20 is formed at least in the front surface (upper surface)region of the substrate 10, as shown in FIG. 2. The defect free layer 20is formed at the beginning of the wafer process. In some embodiments,the defect free layer 20 is formed before any ion implantation,patterning or film formation operations. In other words, the operationsfor forming the defect free layer 20 are performed on a so-called “barewafer” as manufactured by a wafer manufacturer.

In one embodiment, a thermal treatment is performed to form the BMD freelayer 20. The thermal treatment may include a rapid thermal annealing(RTA) method, heating in a furnace or a laser annealing method. Thethermal treatment is performed on the substrate 10 after cleaning thesubstrate 10.

In the thermal treatment, the substrate 10 is heated at a temperature ina range from about 1150° C. to about 1300° C., in some embodiments. Incertain embodiments, the substrate 10 is heated at a temperature in arange from about 1200° C. to about 1250° C. The temperature is increasedfrom, for example, room temperature (25° C.), to the desired temperatureat a temperature increasing rate in a range from about 50° C./sec toabout 100° C./sec, in some embodiments. The thermal treatment isperformed for a time period in a range from about 5 sec to about 20 secin some embodiments. In certain embodiments, the thermal treatment isperformed for a time period in a range from about 10 sec to about 15sec. After the thermal treatment is performed at the above temperature,a cooling process is performed at a cooling rate in a range from about10° C./sec to about 30° C./sec, in some embodiments. In certainembodiments, the cooling process is performed at a cooling rate in arange from about 15° C./sec to about 25° C./sec. The cooling rate islower than the temperature increasing rate. It is noted that a lowercooling rate can create a wider defect free layer. The cooling processmay be performed by multiple steps with different cooling rates. In someembodiments, a fast cooling operation with a first cooling rate isperformed followed by a slow cooling operation with a second coolingrate lower than the first cooling rate. In such a case, the firstcooling rate is in a range from about 15° C./sec to about 30° C./sec andthe second cooling rate is in a range from about 10° C./sec to about 25°C./sec. Three or more steps of reducing the cooling rate may beperformed. In certain embodiments, the cooling rate is graduallydecreased.

By adjusting one or more of the temperature, the process time and thecooling rate, the thickness (depth) D1 of the defect free layer 20 canbe controlled. In some embodiments, the thickness D1 of the defect freelayer 20 is in a range from about 30 μm to about 200 μm. In certainembodiments, D1 is equal to or more than about 50 μm and equal to orless than 100 μm, and in other embodiment, D1 is in a range about 60 μmto about 90 μm. The remaining layer of the substrate 10 is referred toas a bulk layer 30, which still contains BMDs equal to or more than1×10⁸ cm⁻³. It is noted that the defect free layer 20 should not be madetoo thick, because the BMDs in the silicon layer below electronic deviceact as gettering sites.

The density of BMDs in the defect free layer 20 is substantially zero(e.g., less than 100 cm⁻³). In certain embodiment, the density of BMDsin the defect free layer 20 is zero.

In certain embodiment, depending on a method of thermal treatment, adefect free layer is also formed in the bottom (rear) surface of thesubstrate 10.

After the defect free layer 20 is formed, isolation structures (e.g.,shallow trench isolation (STI)) is formed, ion implantation operationsare performed, and electronic devices such as MOS FETs, metal wiringsand contacts, etc. are fabricated on the defect free layer 20, as shownin FIG. 3. In FIG. 3, only a MOS FET 40 covered by an interlayerdielectric (ILD) layer 50 and a contact 45 passing through the ILD layer50 are illustrated as a conceptual illustration of the electronicdevices. Of course, multiple layers of wiring layers, interlayerdielectric layers and vias/contacts, or other passive or activeelectronic devices are also formed on the substrate 10 to provide thedesired structural and functional requirements of the overall circuitdesign. The electronic devices may be formed using any suitable methodseither within or on the surface of the substrate.

The ILD layer 50 is formed over the substrate 10 and the electronicdevice 40 by chemical vapor deposition (CVD), sputtering, or any othersuitable method. The ILD layer 50 typically has a planarized surface andmay be comprised of silicon oxide, although other materials, such aslow-k materials, could alternatively be utilized.

The contact 45 extends through the ILD layer 50 to make electricalcontact with at least one of the electronic devices 40. The contact 45may be formed through the ILD layer 50 by using photolithography andetching techniques. The contact 45 may comprise a barrier/adhesion layer(not shown) to prevent diffusion and provide better adhesion between thecontact 45 and the ILD layer 50. In an embodiment, the barrier layer isformed of one or more layers of titanium, titanium nitride, tantalum,tantalum nitride, or the like. The barrier layer may be formed throughCVD, sputtering or other techniques. The barrier layer may be formed toa combined thickness of about 1 nm to about 50 nm in some embodiments.The contact 45 may be formed of any suitable conductive material, suchas a highly-conductive, low-resistive metal, elemental metal, transitionmetal, or the like. In an exemplary embodiment, the contacts 45 areformed of tungsten, although other materials, such as copper, nickel,cobalt, aluminum or an alloy thereof could alternatively be utilized.

As shown in FIG. 4, an opening 60 is formed through the ILD layer 50 andinto the defect free layer 20 of the substrate 10. In the presentdisclosure, the opening 60 does not reach the bulk layer 30 of thesubstrate 10, as shown in FIG. 4. A distance between the bottom of theopening 60 and the bulk layer 30 is in a range from about 50 nm to about200 nm in some embodiments.

The opening 60 may be formed by applying and developing a suitablephotoresist (not shown), and then etching the ILD layer 50 and at leasta portion of the defect free layer 20 of the substrate 10. The opening60 is formed so as to extend into the substrate 10 at least further thanthe electronic devices 40 formed within but not to reach the bulk layer30. Accordingly, the depth D2 of the opening measured from the uppersurface of the substrate 10 is less than the thickness D1 of the defectfree layer 20. In some embodiments, the depth D2 is about 70% to about95% of the thickness D1 of the defect free layer 20, and in certainembodiments, D2 is about 80% to about 90% of D1. Further, the opening 60has a diameter W1 in a range from about 2 μm to about 70 μm, in someembodiment.

However, in other embodiments, the opening 60 may be formed concurrentlywith or before the formation of the ILD layer 50. Any method offormation to form the opening 60 is included within the scope of thepresent subject matter.

After the opening 60 is formed, a barrier layer 70 and a main conductivelayer 75 are formed in the opening 60 and over the upper surface of theILD layer 50, as shown in FIG. 5. The barrier layer 70 is conformallyformed to cover the sidewalls and the bottom of the opening 60, but doesnot completely fill the opening 60. The thickness of the barrier layer70 is in a range from about 1 nm to about 100 nm in some embodiments,and is in a range from about 2 nm to about 10 nm in other embodiments.By forming the barrier layer 70 conformally, the barrier layer will havea substantially equal thickness along the sidewalls of the opening 60and also along the bottom of the openings 60.

The barrier layer 70 may be formed using a process that will promote aconformal formation, such as plasma enhanced CVD, plasma enhancedphysical vapor deposition (PEPVD) and atomic layer deposition (ALD).

The barrier layer 70 comprises one or more layers of Ti, TiN, Ta ad TaN.Additionally, in some embodiments, the barrier layer 70 may be alloyedwith an alloying material such as carbon or fluorine, although thealloyed material content is generally no greater than about 15% of thebarrier layer 70, and may be less than about 5% of the barrier layer 70.The alloying material may be introduced by one of the precursors duringformation of the barrier layer 70 in the ALD, PECVD, or PEPVD processes.

The main conductive layer 75 may comprise copper, although othersuitable materials such as aluminum, alloys thereof, doped polysilicon,combinations thereof, may alternatively be utilized. The main conductivelayer 75 may be formed by electroplating copper onto the barrier layer70, filling and overfilling the openings 60. In some embodiments, a seedlayer (not shown) is formed on the barrier layer before forming the mainconductive layer 75.

Once the openings 60 have been filled, excess barrier layer 70 and mainconductive layer 75 outside of the openings 60 are removed through aplanarization process such as chemical mechanical polishing (CMP), asshown in FIG. 6, thereby forming a via 80.

FIG. 7 illustrates further process operations in the formation of a TSV.A metal layer 95 is formed over the ILD layer 50 to connect the contact45 and the via 80. The metal layer 95 may be formed by CVD, PVD or othersuitable methods. Although the contact 45 and the via 80 are directlyconnected by one metal layer 95 in FIG. 7, this merely an illustrationof the concept of metal wiring. The contact 45 and the via 80 may beelectrically connected by two or more metal layers formed in the same ordifferent wiring layers.

Further, a passivation layer 90 is further formed over the metal layer95, in order to seal and protect the metal layer 95. The passivationlayer 90 may include a dielectric material such as an oxide or siliconnitride, although other suitable dielectrics, such as a high-kdielectric or polyimide, may alternatively be used. The passivationlayer 90 may be formed using a PECVD process, although any othersuitable process may alternatively be used. The thickness of thepassivation layer 90 is in a range from about 0.6 μm to about 1.5 μm insome embodiments.

In certain embodiments, the passivation layer 90 is patterned to exposeat least a portion of the metal layer 95. The passivation layer 90 maybe patterned using a suitable photolithographic technique. In theopening, a front connection terminal (not shown) is formed.

After the fabrication process for the front side of the substrate iscompleted, the bulk layer 30 and a bottom portion of the defect freelayer 20 are removed, as shown in FIG. 8, to expose the conductivematerial 75 of the via 80 located within the opening 60 to complete aTSV. The removal may be performed with a grinding process such as achemical mechanical polishing (CMP) method, although other suitableprocesses, such as etching, may alternatively be used. The bulk layer 30is completely removed and the defect free layer 20 is partially removedsuch that the remaining thickness D3 of the defect free layer 20 becomesa desired thickness. The thickness D3 is about 50% to about 90% of thethickness D1, in some embodiments. In certain embodiments, D3 is in arange from about 30 μm to about 50 μm.

After the bottom of the via 80 is exposed, a bottom connection terminal97 is formed as shown in FIG. 9. In some embodiments, an upperconnection terminal 98 is formed on the metal layer 95 for an externalconnection. The upper and bottom connection terminals may comprise aconductive layer, such as Ni, Au or an alloy thereof.

As shown in FIG. 9, the TSV 80 in the substrate is surrounded by thedefect free layer 20 in the substrate, and no bulk layer containing BMDsis in contact with the TSV 80.

In other embodiments, as shown in FIG. 10, two substrates areelectrically connected through the via (TSV) 80. In FIG. 10, a firstsubstrate 100 has a similar structure as the structure show in FIG. 8. Asecond substrate 200 is formed by the operations disclosed with respectto FIGS. 1-9, and includes a defect free layer 120, electronic devices140, a contact 145, a first ILD layer 150, two TSVs 180, 181, metallayers 194, 195, a second ILD layer 190, and bottom connection terminals196, 197. The second substrate 200 further includes a connectionterminal 198, by which the first substrate 100 and the second substrate200 are electrically connected. Of course, more than two substrates canbe stacked by a similar manner.

FIGS. 11 and 12 show exemplary cross sectional views illustrating amanufacturing process of a TSV structure according to one embodiment ofthe present disclosure. The similar or the same configurations,dimensions, processes, materials and/or structures as set forth abovemay be employed in the following embodiment, and the detailedexplanation may be omitted.

In FIG. 11, a substrate 15 is provided. The substrate 15 has the sameconfiguration as the substrate 10. As shown in FIG. 12, an epitaxiallayer 20′ is formed over the substrate 15. In this embodiment, forexample, the substrate 15 is a Si substrate (wafer) and the epitaxiallayer 20′ is a Si epitaxial layer. After the epitaxial layer 20′ isformed, the operations disclosed with respect to FIGS. 3-9 areperformed.

Since the layer 20′ is formed by an epitaxial growth method, theepitaxial layer 20′ is substantially defect-free (i.e., the defect freelayer). The density of BMDs in the defect free layer 20′ issubstantially zero (e.g., less than 100 cm⁻³). In certain embodiments,the density of BMDs in the defect free layer 20′ is zero.

In some embodiments, the thickness D1′ of the defect free layer 20′ isin a range from about 30 μm to about 200 μm. In certain embodiments, D1is equal to or more than about 50 μm. The substrate 15 can be referredto as a bulk layer 30′, which still contains BMDs equal to or more than1×10⁸ cm⁻³. Similar to the foregoing embodiment, the thickness D1′ ofthe defect free layer 20′ is such a thickness that the bottom of theopening 60 (see, FIG. 4) does not reach the substrate 15 (bulk layer30′).

FIG. 13 shows an exemplary cross sectional view illustrating amanufacturing process of a TSV structure according to another embodimentof the present disclosure. The similar or the same configurations,dimensions, processes, materials and/or structures as set forth abovemay be employed in the following embodiment, and the detailedexplanation may be omitted.

In this embodiment, the defect free region 22 is selectively foamed inan area 81 of the substrate 10, where the opening 60 (TSV 80) (see,FIGS. 4 and 6) is subsequently formed. To selectively apply heat to formthe defect free region 22, for example, a laser annealing method 300 canbe used. By applying the laser 300, the substrate 10 is locally heatedat about 1200° C. to about 1250° C., and the heated area becomes a BMDfree region 22.

The laser 300 may also be applied from the back side of the substrate10. In such a case, the BMD free region 22 may be formed from the frontsurface to the back surface of the substrate 10. Further, an opening 60(see, FIG. 4) may be formed deeper than the case of FIG. 4.

FIGS. 14 and 15 show exemplary cross sectional views illustrating amanufacturing process of a TSV structure according to another embodimentof the present disclosure. The similar or the same configurations,dimensions, processes, materials and/or structures as set forth abovemay be employed in the following embodiment, and the detailedexplanation may be omitted.

In this embodiment in an area 81 of the substrate 10, where the opening60 (TSV 80) is subsequently formed.

As shown in FIG. 14, the substrate 10 is etched by using a mask pattern410 to form an opening 420 in an area 81 of the substrate 10, where theopening 60 (TSV 80) is subsequently formed. The mask pattern 410 mayinclude one or more layers of silicon oxide and silicon nitride. Withthe mask pattern 410 remaining on the substrate 10, a selectiveepitaxial growth is performed to form an epitaxial layer 23, i.e., adefect free layer, in the opening 420. Subsequently, the mask pattern410 is removed. In some embodiments, a planarization operation, such aschemical mechanical polishing (CMP), is used to remove an excessepitaxial layer.

The various embodiments or examples described herein offer severaladvantages over the existing art. For example, in the presentdisclosure, since a defect free layer is formed in or on the substrateand an opening for a TSV does not reach a bulk layer with BMDs, it ispossible to prevent adverse effects on the TSV otherwise caused by BMDs.Further, since the bulk layer with BMDs still remains under theelectronic devices, it is possible to utilize the bulk layer as a metalimpurity gettering layer.

It will be understood that not all advantages have been necessarilydiscussed herein, no particular advantage is required for allembodiments or examples, and other embodiments or examples may offerdifferent advantages.

In accordance with one aspect of the present disclosure, in a method ofmanufacturing a semiconductor device, a thermal treatment is performedon a substrate, thereby forming a defect free layer in an upper layer ofthe substrate, where a remaining layer of the substrate is a bulk layer.The bulk layer contains bulk micro defects as defects and a density ofthe defects in the bulk layer being equal to or more than 1×10⁸ cm⁻³. Anelectronic device is formed over the defect free layer. An opening isformed in the defect free layer such that the opening does not reach thebulk layer. The opening is filled with a conductive material, therebyforming a via. The bulk layer is removed so that a bottom part of thevia is exposed. A density of defects in the defect free layer is lessthan 100 cm⁻³.

In accordance with another aspect of the present disclosure, in a methodof method of manufacturing a semiconductor device, an electronic deviceis formed over a substrate having a defect free layer and a bulk layer.The bulk layer contains bulk micro defects as defects and a density ofthe defects in the bulk layer being equal to or more than 1×10⁸ cm⁻³. Anopening is formed in the defect free layer such that the opening doesnot reach the bulk layer. The opening is filled with a conductivematerial, thereby forming a via. The bulk layer is removed so that abottom part of the via is exposed. A density of defects in the defectfree layer is less than 100 cm⁻³.

In accordance with another aspect of the present disclosure, asemiconductor device comprising, a first substrate with a firstelectronic device and a connection terminal electrically connected tothe first electronic device; and a second substrate with a secondelectronic device and a via passing through the second substrate andelectrically connected to the second electronic device. The firstsubstrate is attached to the second substrate so that the connectionterminal is in contact with the via, and the via is surrounded by adefect free layer of the second substrate. A density of defects in thedefect free layer is less than 100 cm⁻³, where the defects are bulkmicro defects.

The foregoing outlines features of several embodiments or examples sothat those skilled in the art may better understand the aspects of thepresent disclosure. Those skilled in the art should appreciate that theymay readily use the present disclosure as a basis for designing ormodifying other processes and structures for carrying out the samepurposes and/or achieving the same advantages of the embodiments orexamples introduced herein. Those skilled in the art should also realizethat such equivalent constructions do not depart from the spirit andscope of the present disclosure, and that they may make various changes,substitutions, and alterations herein without departing from the spiritand scope of the present disclosure.

What is claimed is:
 1. A method of manufacturing a semiconductor device,comprising: performing a thermal treatment on a part of a substrate,thereby forming a defect free region in an upper layer of the substrate,a remaining layer of the substrate being a bulk layer; forming anelectronic device over the defect free layer; forming an opening in thedefect free region such that the opening does not reach the bulk layer;filling the opening with a conductive material, thereby foaming a via;and removing the bulk layer so that a bottom part of the via is exposed,wherein a density of defects in the defect free layer is less than 100cm⁻³.
 2. The method of claim 1, wherein the density of defects in thedefect free layer is zero.
 3. The method of claim 1, wherein a thicknessof the defect free layer before forming the electronic device is in arange from 30 μm to 200 μm.
 4. The method of claim 3, wherein a depth ofthe opening is 70% to 90% of the thickness of the defect free layer. 5.The method of claim 1, wherein in the thermal treatment, the substrateis heated at a temperature in a range from 1200° C. to 1250° C.
 6. Themethod of claim 5, wherein the thermal treatment is performed by a laserannealing.
 7. The method of claim 1, wherein the filling the openingwith a conductive material includes: forming a barrier layer; andforming a main conductive layer on the barrier layer.
 8. The method ofclaim 7, wherein the barrier layer includes at least one of TiN, Ti, TaNand Ta, and the main conductive layer includes Cu or a Cu alloy.
 9. Themethod of claim 1, wherein further comprising forming a passivationlayer over the via.
 10. The method of claim 1, further comprising:attaching another substrate having a connection terminal to a bottomsurface of the substrate where the via is exposed so that the exposedvia is connected to the connection terminal.
 11. The method of claim 1,wherein the bulk layer contains bulk micro defects as defects and adensity of the defects in the bulk layer being equal to or more than1×10⁸ cm⁻³.
 12. A method of manufacturing a semiconductor device,comprising: forming a first opening by partially etching a part of asubstrate; forming an epitaxial layer in the first opening; forming anelectronic device over the substrate; forming a second opening in theepitaxial layer such that the second opening does not reach a bottom ofthe epitaxial layer; filling the second opening with a conductivematerial, thereby forming a via; and removing a part of a rear surfaceof the substrate so that a bottom part of the via is exposed, wherein adensity of defects in the epitaxial layer is less than 100 cm⁻³.
 13. Themethod of claim 12, wherein the substrate other than the epitaxial layercontains bulk micro defects as defects and a density of the defects inthe bulk layer being equal to or more than 1×10⁸ cm⁻³.
 14. The method ofclaim 13, wherein a thickness of the epitaxial layer is in a range from30 μm to 200 μm.
 15. The method of claim 14, wherein a depth of thesecond opening is 70% to 90% of the thickness of the epitaxial layer.16. The method of claim 12, wherein the filling the opening with aconductive material includes: forming a barrier layer; and forming amain conductive layer on the barrier layer.
 17. The method of claim 16,wherein the barrier layer includes at least one of TiN, Ti, TaN and Ta,and the main conductive layer includes Cu or a Cu alloy.
 18. The methodof claim 12, wherein further comprising forming a passivation layer overthe via.
 19. The method of claim 12, further comprising: attachinganother substrate having a connection terminal to a bottom surface ofthe substrate where the via is exposed so that the exposed via isconnected to the connection terminal.
 20. A semiconductor devicecomprising: a substrate; an electronic device disposed over thesubstrate; a dielectric layer disposed over the electronic device; a viapassing through the dielectric layer and the substrate and electricallyconnected to the electronic device; a bottom electrode connected to thevia; and a passivation layer provided over the dielectric layer,wherein: a density of defects in the substrate is less than 100 cm⁻³,the defects are bulk micro defects, and the bottom electrode is incontact with a rear surface of the substrate having the density ofdefects in the substrate less than 100 cm⁻³.